发明名称 Derivatives of 4-(methylphosphinyl)-2-oxobutanoic acid, herbicidal compositions containing them, and intermediates and methods for their production.
摘要 <p>There are described compounds of the formula &lt;Chemistry id="chema01" num="0001"&gt;&lt;Image id="ia01" he="24" wi="77" file="IMGA0001.TIF" imgContent="chem" imgFormat="TIFF" inline="no" /&gt;&lt;/Chemistry&gt;in which R&lt;Sup&gt;5&lt;/Sup&gt; is methyl or halomethyl, &lt;UnorderedLists id="ula01" listStyle="none"&gt;&lt;ListItem&gt;R&lt;Sup&gt;2&lt;/Sup&gt; is -CN, -CONRyRz, -COOR&lt;Sup&gt;6&lt;/Sup&gt; or -&lt;Sub&gt;COS&lt;/Sub&gt;R&lt;Sup&gt;6&lt;/Sup&gt;,&lt;/ListItem&gt;&lt;ListItem&gt;R&lt;Sup&gt;1&lt;/Sup&gt; and R&lt;Sup&gt;6&lt;/Sup&gt; each represent hydrogen, a cation or an optionally substituted alkyl, alkenyl, alkynyl or aryl,&lt;/ListItem&gt;&lt;ListItem&gt;Ry and Rz each represent hydrogen, alkyl or aryl,&lt;/ListItem&gt;&lt;ListItem&gt;A represents hydrogen, or A and one of -XR&lt;Sup&gt;3&lt;/Sup&gt; and -ZR&lt;Sup&gt;4&lt;/Sup&gt; together form a double bond, and the other of -XR&lt;Sup&gt;3&lt;/Sup&gt; and -ZR&lt;Sup&gt;4&lt;/Sup&gt; represents -OR&lt;Sup&gt;10&lt;/Sup&gt; or -NHR&lt;Sup&gt;11&lt;/Sup&gt; in which R&lt;Sup&gt;10&lt;/Sup&gt; is alkyl or acyl and R&lt;Sup&gt;11&lt;/Sup&gt; is alkyl, aryl or acyl,&lt;/ListItem&gt;&lt;ListItem&gt;X and Z (when not forming part of a double bond with A), which may be the same or different, each represent oxygen, sulphur or a group -NR&lt;Sup&gt;7&lt;/Sup&gt;-,&lt;/ListItem&gt;&lt;ListItem&gt;R&lt;Sup&gt;7&lt;/Sup&gt; represents hydrogen or alkyl,&lt;/ListItem&gt;&lt;ListItem&gt;R&lt;Sup&gt;3&lt;/Sup&gt; and R&lt;Sup&gt;4&lt;/Sup&gt; each represent alkyl or R&lt;Sup&gt;3&lt;/Sup&gt; and R&lt;Sup&gt;4&lt;/Sup&gt; together form an optionally substituted alkylene or arylene chain&lt;/ListItem&gt;&lt;ListItem&gt;or -XR&lt;Sup&gt;3&lt;/Sup&gt; and &lt;Sup&gt;-ZR4&lt;/Sup&gt; together form &lt;Sup&gt;=C&lt;/Sup&gt;(&lt;Sup&gt;CN&lt;/Sup&gt;)&lt;Sup&gt;2&lt;/Sup&gt; or &lt;Sup&gt;=NR8&lt;/Sup&gt;, in which R&lt;Sup&gt;8&lt;/Sup&gt; represents alkoxy, benzyloxy, hydroxy, phenyl, -NHCONH&lt;Sub&gt;2&lt;/Sub&gt;, -NHCSNH&lt;Sub&gt;2&lt;/Sub&gt; or -NH phenyl,&lt;/ListItem&gt;&lt;ListItem&gt;or one of -XR&lt;Sup&gt;3&lt;/Sup&gt; and -ZR&lt;Sup&gt;4&lt;/Sup&gt; is -OH (or an ester or ether thereof) and the other is hydrogen, -CN or -SO&lt;Sub&gt;3&lt;/Sub&gt;&lt;Sup&gt;⊖&lt;/Sup&gt;cation,&lt;/ListItem&gt;&lt;ListItem&gt;or -XR&lt;Sup&gt;3&lt;/Sup&gt; and -ZR&lt;Sup&gt;4&lt;/Sup&gt; together form carbonyl oxygen.&lt;/ListItem&gt;&lt;ListItem&gt;There are also described methods for making the compounds and herbicidal compositions containing them.&lt;/ListItem&gt;&lt;/UnorderedLists&gt;</p>
申请公布号 EP0030424(A2) 申请公布日期 1981.06.17
申请号 EP19800304137 申请日期 1980.11.19
申请人 FISONS PLC 发明人 BAILLIE, ALISTER CAMERON;WRIGHT, BRIAN JOHN;WRIGHT, KENNETH;EARNSHAW, CHRISTOPHER GEOFFREY
分类号 A01N57/24;C07F9/30;C07F9/32;C07F9/6539;A01N57/18;A01N57/20;(IPC1-7):07F9/30;07F9/65;01N57/20;01N57/24;07F9/32 主分类号 A01N57/24
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