发明名称 |
MESOPOROUS CRYSTALLINE SOLID COMPOUND OF A DIPHOSPHONATE/PHOSPHITE OF A TETRAVALENT METAL, WITH A NARROW DISTRIBUTION OF MESOPORES |
摘要 |
The present invention discloses a compound comprising a diphosphonate/phosphite of a tetravalent metal: M[(O3P-R-PO3)1-(x+y) (HPO3)2X(O3P-R-PO3H2)2y] (where M, R, x and y have the meaning given in the description), in the form of a crystalline solid with an alpha-type lamellar structure with a distance between layers of 7.4 to 20 ANGSTROM (depending on the dimensions of radical R), a BET surface area of 250 to 400m2/g, and porosity within the mesopore range, with at least 50% of the pores measuring 20 to 30 ANGSTROM . The compound, depending on the radical R used, may or may not have microporosity in the region between layers. Such a diphosphonate/phosphite of a tetravalent metal is obtained by reaction between diphosphonic acid, phosphorous acid and an oxyhalide of a tetravalent metal, in a solvent comprising dimethyl-sulphoxide/water containing hydrofluoric acid.
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申请公布号 |
US5166380(A) |
申请公布日期 |
1992.11.24 |
申请号 |
US19910738891 |
申请日期 |
1991.08.01 |
申请人 |
ENIRICERCHE S.P.A. |
发明人 |
ALBERTI, GIULIO;COSTANTINO, UMBERTO;VIVANI, RICCARDO;ZAPPELLI, PIERGIORGIO;ROSSODIVITA, ANTONIO;BASSIGNANI, LUCIANO |
分类号 |
C07F9/40;B01J20/02;B01J29/03;B01J29/04;C07F7/00;C07F9/02;C07F9/38 |
主分类号 |
C07F9/40 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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