| 摘要 |
The invention relates to a process for the preparation of organoinorganic materials by an electron transfer reaction in the solid state between two organic versus inorganic redox antagonists. These organoinorganic materials comprise an electron donor D and an electron acceptor A, D and A being two redox antagonists, one of which is inorganic and the other is organic, and they are obtained by an electron transfer reaction in the solid state between two powders, one of which comprises the electron donor D and the other comprises the electron acceptor A. D can be, for example, tetrathiafulvalene and its derivatives, KI, K4Fe(CN)6.3H2O or Cu. A can be, for example, CuClOH, FeOCl, Cu(SCN)2 or tetracyanoquinodimethane.
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