VERFAHREN ZUR HERSTELLUNG VON TEILWEISE NEUTRALISIERTEN, STARK SAUREN KATIONAUSTAUSCHHARZEN IN SAURER FORM.

摘要

This invention is a process for preparing an insoluble strong-acid cation-exchange resin in acid form modified by the partial neutralization of its cation-exchange capacity with aminoalkanethiol. The process is characterized by contacting the cation-exchange resin with an N-(2-mercaptoalkyl) amide in the presence of water under reaction condition sufficient to produce the modified cation-exchange resin. The partially neutralised resin can be treated further by contacting it with an aldehyde or ketone under reaction conditions sufficient to convert the aminoalkanethiol moieties to thiazolidine moieties. These partly neutralised resins are useful as catalysts in the preparation of bisphenols from phenol and carbonyl compounds.