发明名称 PROCESS FOR THE ENZYMATIC RESOLUTION OF 2-AMINO-4-METHYL- PHOSPHINOBUTYRIC ACID DERIVATIVES
摘要 <p>L-PTC (L-phosphinothricin, L-2-amino-4-methylphosphinobutyric acid) is the active herbicidal component in D,L-PTC and can be obtained according to the invention by treating D,L-PTC derivatives which are N-acylated and esterified on the phosphinic acid group, as well as optionally esterified or amidated on the carboxyl group, with an enzyme with hydrolytic activity in aqueous or aqueous-organic medium, whereupon the L-PTC derivatives are selectively hydrolysed at the N-acyl group or the modified carboxyl group, the resulting product mixture is separated, and the required L-PTC derivative is hydrolysed to L-PTC and isolated by customary methods.</p>
申请公布号 AU627546(B2) 申请公布日期 1992.08.27
申请号 AU19900049117 申请日期 1990.02.06
申请人 HOECHST AKTIENGESELLSCHAFT 发明人 LOTHAR WILLMS;GERD FULLING;REINHOLD KELLER
分类号 C07F9/30;C07F9/32;C12P13/02;C12P13/04;C12P41/00;(IPC1-7):C12P41/00 主分类号 C07F9/30
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