发明名称 PRODUCTION OF ORTHO-ALKYLANILINES
摘要 PURPOSE:To obtain the subject compound useful as an intermediate for agricultural chemicals, dyeing assistant, etc., in high selectivity, conversion and yield by reacting an aniline compound with an olefin in liquid phase in the presence of a solid acid catalyst consisting of a cation-exchanged laminar compound. CONSTITUTION:The subject compound can be produced in high selectivity on an industrial scale at a low cost by reacting an aniline compound with an olefin in liquid phase in the presence of a solid acid catalyst consisting of a laminar compound exchanged with a cation, e.g. >=2-valent metallic ion selected from Al, Ca, Fe, Ni, Cu, Ga, In, Se, La, Zr and/or Ti, e.g. montmorillonite, bentonite, hectorite, taeniolite, saponite, vermiculite and/or tetrasilicic mica or a material produced by crosslinking the above laminar compound with a metal oxide such as alumina, zirconia, iron oxide or titanium oxide.
申请公布号 JPH04154743(A) 申请公布日期 1992.05.27
申请号 JP19900276910 申请日期 1990.10.16
申请人 MITSUI PETROCHEM IND LTD 发明人 NAGATA TAKUJI;YASUHARA MITSUTATSU;FUJITA TERUNORI
分类号 B01J21/16;C07B61/00;C07C209/68;C07C211/45 主分类号 B01J21/16
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