| 摘要 |
<p>The invention relates to a process for the production of a bisphenol comprising the steps of: (a) reacting a carbonyl compound with a stoichiometric excess of a phenolic compound in the presence of an effective amount of an acidic catalyst to produce a reaction product mixture comprising a bisphenol and a bisphenol by-product; (b) passing at least a portion of said reaction product mixture to a crystallization zone maintained under conditions effective to produce a crystalline bisphenol and a mother liquor comprising the bisphenol by-product; (c) contacting, in an isomerization zone, at least a portion of said mother liquor with an acidic ion exchange resin isomerization catalyst under conditions effective to convert at least a portion of said bisphenol by-product to said bisphenol, to produce a isomerization reaction product mixture comprising the bisphenol; (d) contacting the isomerization reaction product mixture with a guard bed selected from the group consisting of alumina, silica, titanium oxide, zirconium oxide, tin oxide, carbon, and silicon carbide; and (e) recovering the bisphenol from the thus-treated isomerization reaction product mixture. c</p> |
