| 摘要 |
<p>Continuous manufacture of 1,1,1-chlorodifluoroethane from 1,1,1-trichloroethane and hydrofluoric acid by liquid phase reaction in the presence of at least one fluorination catalyst. According to the invention the operation is carried out at an absolute pressure of between 6 and 30 bars and at a temperature of between 50 and 120 DEG C, the catalyst content of the reaction mixture, expressed as weight percentage of metal, being between 0.05 and 10% and its content of organohalogen by-products outside 140 series being regulated at a value of less than 40% by weight. This process makes it possible simultaneously to obtain a high degree of conversion of hydrofluoric acid, to minimise the coproduction of 1,1,1-trifluoroethane and of organohalogen by-products, and to make it easier to recover the hydrochloric acid formed.</p> |
