发明名称 PRODUCTION OF (METH)ACRYLIC ACID ESTER
摘要 PURPOSE:To obtain the subject compound in high purity by providing the same alcoholic residues of a raw material and a catalyst in reacting methyl or ethyl (meth)acrylate with a 3-20C alcohol in the presence of a tetraalkyl titanate catalyst. CONSTITUTION:Methyl or ethyl(meth)acrylate is reacted with a 3-20C alcohol expressed by the formula ROH (R is alcoholic residue), preferably cylohexanol, benzyl alcohol, phenylethanol, methoxyethanol, ethoxyethanol, N,N- dimethylaminoethanol, N,N-diethylaminoethanol and/or 2-cyanoethanol in the presence of a tetraalkyl titanate, expressed by the formula Ti(OR)4 and having the same alcoholic residue (R) as that of the aforementioned compound to afford the subject compound useful in various fields of resins, coatings, adhesives, industrial materials, etc., in high purity and quality.
申请公布号 JPH0466555(A) 申请公布日期 1992.03.02
申请号 JP19900174549 申请日期 1990.07.03
申请人 MITSUBISHI GAS CHEM CO INC 发明人 HONMA AKIHIRO;KUROKAWA MASAHIRO
分类号 B01J31/02;C07B61/00;C07C67/02;C07C69/54 主分类号 B01J31/02
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