发明名称 PROCESS FOR THE PREPARATION OF SUBSTITUTED PYRIDINES VIA 1-AZA-1,3-BUTADIENES AND THE 1-AZA-1,3-BUTADIENE INTERMEDIATES
摘要 PCT No. PCT/NL91/00148 Sec. 371 Date May 21, 1993 Sec. 102(e) Date May 21, 1993 PCT Filed Aug. 7, 1991 PCT Pub. No. WO92/02505 PCT Pub. Date Feb. 20, 1992.Process for the preparation of substituted pyridines by allowing 1-aza-1,3-butadienes to react, in the presence of a catalytic amount of secondary amine and acid, with an aldehyde or ketone, and new 1-aza-1,3-butadienes which are used in this process. Said pyridines can be obtained in high yield in a simple process with a short reaction time. The 1-aza-1,3-butadiene can, if so desired, be prepared in situ from an imine and an aldehyde.
申请公布号 AU8394191(A) 申请公布日期 1992.03.02
申请号 AU19910083941 申请日期 1991.08.07
申请人 DSM N.V. 发明人 ANNA MARIA CORNELIA FRANCISCA CASTELIJNS;HENRICUS JOHANNES ARTS
分类号 C07C251/12;C07C251/14;C07C251/16;C07C251/40;C07C317/26;C07C323/23;C07D213/08;C07D213/09;C07D213/12;C07D215/06 主分类号 C07C251/12
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