New azolyl:methyl-substd. cyclic alcohol derivs.

摘要

(A)Azolylmethyl-substd. cyclic alcohols of formula (I) and their acid-addn. salts and metal complexes are new. X= CH or N; T= (CH2)n, CR11R12, O or S; n= 1-5; R1 and R5= H or 1-4C alkyl, or CR1R5= C=CHR7 or CHZR'7; Z=CH2, O, SO, SO, SO2 or NR8; R7= (a) 1-8C alkyl, phenyl, biphenylyl, naphthyl, benzyl or 3-8C cycloalkyl, all opt. substd. by 1-3 of halogen, NO2, OPh, NH2, 1-4C alkyl, 1-4C alkoxy, or 1-4C haloalkyl, or (b) tetrahydropyranyl; R'7= H or R7; R2 and R3= H or 1-4C alkyl, or CR2R3 may be C=CHR7 when CR1R5 is C=CHR7; R4 and R8= H or 1-4C alkyl; or R3+R4 completes a satd. or unsatd. 5-6C carbocyclic ring; R6 and R9-R12= 1-8C alkyl, phenyl, biphenylyl, naphthyl, heteroaryl, benzyl, dioxolanyl or 3-8C cycloalkyl, all opt. substd. by 1-3 of halogen, NO2, OPh, NH2, 1-4C alkyl, 1-4C alkoxy or 1-4C haloalkyl; or R2+R3+R4+R9 completes an opt. halo-substd. benzene ring; etc.