PROCESS AND CATALYST FOR THE CONVERSION OF CO/H2O MIXTURES

摘要

The conversion of CO/H2O mixtures, in particular water gas, is carried out in the presence of solid, polymer rhodium complex catalysts which are insoluble in aqueous and organic solvents and are obtainable by polycondensation of one or more rhodium complexes having at least one ligand which contains at least one group capable of coordinating to rhodium and at least one group forming an inorganic network in the polycondensation, either with itself or with one or more inorganic network-forming agents capable of undergoing polycondensation. Novel rhodium complexes of this type are also described.