发明名称 |
PROCESS USING TRANSITION METAL COMPLEXES FOR THE SEPARATION OF DIOXYGEN FROM A GAS MIXTURE BY ELECTRODECOMPLEXATION |
摘要 |
PCT No. PCT/FR91/00218 Sec. 371 Date Nov. 6, 1991 Sec. 102(e) Date Nov. 6, 1991 PCT Filed Mar. 19, 1991 PCT Pub. No. WO91/14649 PCT Pub. Date Oct. 3, 1991.A process for separating dioxygen from a gaseous mixture containing dioxygen, which entails: a) absorbing dioxygen by one or more transition metal complexes at a low oxidation state of the formula (A): (Ln(M+p)m(X-z)xmp-xz(A) the absorption causing formation of a peroxo dihapto deoxygenated product complex of the formula (B): (Ln'(Mp+2O2)m'(X-z)x)m'p-x'z(B) b) desorbing oxygen from the complex by electrochemically oxidizing the peroxo dihapto product complex obtained by reaction of the complex of the formula (A) wiht O2: and c) recovering the absorbed oxygen. |
申请公布号 |
ZA9102276(B) |
申请公布日期 |
1991.12.24 |
申请号 |
ZA19910002276 |
申请日期 |
1991.03.26 |
申请人 |
L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGE'S CLAUDE |
发明人 |
CHRISTIAN AMATORE;SAID AZIZ;ANNY JUTAND;FRANCOIS DRASKOVIC;KENNETH YAMAGUCHI;PANAYOTIS COCOLIOS |
分类号 |
B01D53/14;C01B13/02;C07F15/00;C25B1/02 |
主分类号 |
B01D53/14 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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