KATALYTISCHE ZUSAMMENSETZUNG UND VERFAHREN ZUR HERSTELLUNG VON KOHLENWASSERSTOFFEN AUS SYNTHESEGAS DAMIT.

摘要

A catalyst composition which contains at least one metal from Group 2b and at least one metal from Group 6b of the Periodic Table of the Elements or compounds thereof and a crystalline trivalent metal (e.g. iron or gallium) silicate which is obtainable by maintaining an aqueous alkaline starting mixture comprising at least one trivalent metal (A) compound, at least one silicon compound, at least one compound of a metal from Group 1a of the Periodic Table of the Elements (MX) and organic nitrogen compounds at an elevated temperature until crystalline metal silicate has formed and subsequently separating crystalling metal silicate from the mother liquor, in which starting mixture the various compounds are present within the following molar ratios: RN : R4NY = 1 - 1000, SiO2 : R4NY = 10 - 5000, SiO2 : A2O3 = 50 - 300, SiO2 : MX < 15, and H2O : SiO2 = 5 - 100, RN representing a pyridine and R4NY representing an organic quaternary ammonium compound. The catalyst composition can be used in a process for the preparation of hydrocarbons from synthesis gas.