POLYCYANAMID-TETRAPHENYLPORPHYRIN

摘要

A metal complex of formula (I) is produced by diazotizing polycyanamide of formula (II) in the thick sulfuric acid, coupling the mixed soln. with tetraphenyl porphyrine of formula (III) to produce polycyanamide- tetraphenyl porphyrine of formula (IV), and forming a complex of (IV) and metal ion. In eht formulas, M is Zn, Mg, Cu, Co, Fe, Ni or Mn; x is 5-30; Y is N2 in the low temp.; n is 500-3000. The metal complex is useful as an conductive polymeric material.