发明名称 |
SELECTIVE 6-ACYLATION OF SUCROSE MEDIATED BY CYCLIC ADDUCTS OF DIALKYLTIN OXIDES AND DIOLS |
摘要 |
There is disclosed a process which comprises the steps of: (a) reacting a di(hydrocarbyl)tin oxide such as a dialkyltin oxide with a dihydric alcohol, alkanolamine, or an enolizable .alpha.-hydroxy ketone in an inert organic reaction vehicle, with removal of water, at a temperature and for a period of time sufficient to produce a cyclic adduct of said dialkyltin oxide and said dihydric alcohol, alkanolamine, or enolizable .alpha.-hydroxy ketone; (b) reacting said cyclic adduct product of Step (a) with sucrose in an inert organic reaction vehicle such as a dipolar aprotic liquid, at a temperature and for a period of time sufficient to produce a 6-O-[dihydrocarbyl- (hydroxy- or amino- or oxohydrocarbyl)stannoxyl]sucrose; and (c) reacting the product of Step (b) with an acylating agent to produce a sucrose-6-ester.
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申请公布号 |
CA2038740(A1) |
申请公布日期 |
1991.09.24 |
申请号 |
CA19912038740 |
申请日期 |
1991.03.21 |
申请人 |
NORAMCO, INC. |
发明人 |
WALKUP, ROBERT E.;VERNON, NICHOLAS M.;WINGARD, ROBERT E., JR. |
分类号 |
C07B61/00;C07F7/22;C07H3/04;C07H13/00;C07H13/04;C07H13/06;C07H13/08;C07H23/00;(IPC1-7):C07H13/02 |
主分类号 |
C07B61/00 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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