摘要 |
<p>A first metal, for example a transition metal such as cobalt, having an insoluble hydroxide is separated from a second metal such as lithium having a soluble hydroxide in an aqueous liquid containing dissolved cations of the metals. The cations are firstly absorbed onto a cation exchange material by electrochemical ion exchange and the second metal then selectively eluted by electrochemical ion exchange under sufficiently high pH conditions, e.g. to 10-13, in a closed loop. Finally, the transition metal is eluted by electrochemical ion exchange under sufficiently low pH conditions, e.g. acidic such as 1-2. The method is applicable to separating trace quantities of Co (e.g. as Co-60) from larger quantities of Li in aqueous solution.</p> |