KLEBENDES, MIT SILAN MODIFIZIERTES ETHENCOPOLYMER UND DESSEN HERSTELLUNG.

摘要

A silane-modified ethylene copolymer is prepared by graft copolymerizing from 0.1 to 10 parts by weight of a trialkoxyvinyl silane (e.g. methoxy or ethoxy) to 100 parts by weight of a copolymer of ethylene, 0.3-12 mol % of a (meth)acrylic acid ester and 0.2-5 mol % of maleic anhydride by melt mixing the reactants at a temperature at least 20 DEG C above the melting point of the polymer, in the presence of a peroxide catalyst (e.g. dicumyl peroxide). The copolymer is used as an adhesive in the form of an extruded film 1-100 mu m thick or a solution,e.g. in trichloroethylene. The silane-modified ethylene copolymer is excellent in adhesion to metals, glass, polar high-molecular weight materials or polyolefins and in maintenance of water-resistant adhesion to glass.