发明名称 |
Process for the preparation and recovery of oxydiphthalic anhydrides |
摘要 |
Oxydiphthalic anhydrides of the formula <IMAGE> are prepared by reacting a halophthalic anhydride with potassium carbonate in: (1) a solvent-free reaction medium wherein the molar ratio of halophthalic anhydride:potassium carbonate is greater than 2:1; or (2) a high boiling solvent which improves the mixing of the components, and aids in subsequent purification of the product. The molar ratio of halophthalic anhydride to potassium carbonate is about 1.5:1 or greater. The oxydiphthalic anhydride can be purified by filtering or centrifuging a hot solution of the oxydiphthalic anhydride in a high boiling solvent to remove impurities, followed by cooling the solution to precipitate the oxydiphthalic anhydride, which can be removed from the solution by filtration or centrifuging.
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申请公布号 |
US5021168(A) |
申请公布日期 |
1991.06.04 |
申请号 |
US19890381345 |
申请日期 |
1989.07.18 |
申请人 |
OCCIDENTAL CHEMICAL CORPORATION |
发明人 |
MOLINARO, JOHN R.;PAWLAK, JOSEPH A.;SCHWARTZ, WILLIS T. |
分类号 |
C07C51/567 |
主分类号 |
C07C51/567 |
代理机构 |
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地址 |
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