摘要 |
Electrically conductive polythiophene and its derivatives are prepared by polymerizing compounds of the formula: <IMAGE> (I) wherein R1 and R2 are independently hydrogen, R3, -OR3 or -SR3; and R3 is aryl of 6 to 12 carbons or aliphatic of 1 to 12 carbons; comprising reacting the compound of formula I in the presence of an initiator, the initiator comprising a 2-substituted thiophene nucleus which has a lower oxidation potential than the compound of formula I and which is capable of being incorporated into the polymer resulting from the polymerization reaction; a chemical oxidant or an applied electrochemical potential; and a non-aqueous organic solvent.
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