摘要 |
Processes for the conversion of hydrocarbons, and most preferably methane, to higher hydrocarbons and olefins are disclosed, including contacting the hydrocarbons with a mixed metal oxide catalyst having the pyrochlore structure. Preferably, thase catalysts have the general formula AnB2O7-x, where A can be various mono-, di-, and trivalent metal cations, B can be various tri-, tetra-, penta-, and hexavalent metal cations, 0 ? n ? 2.0, and 0 ? x ? 1.0. Novel, high surface area, mixed metal oxide catalysts having the pyrochlore structure are also disclosed, including those having the formula A2B2O7, where A is divalent and B is niobium and/or tantalum, and those having the formula A2(Sn2-yAy)O7-z, where A is bismuth and/or lead, 0.0 ? y ? 1.0, and 0.0 ? z ? 1.0. |
申请人 |
JACOBSON, ALLAN J.;HALL, RICHARD B.;MIMS, CHARLES A.;LEWANDOWSKI, JOSEPH T. |
发明人 |
JACOBSON, ALLAN J.;HALL, RICHARD B.;MIMS, CHARLES A.;LEWANDOWSKI, JOSEPH T. |