MONOCOMPONENT POLYSILOXANE COMPOSITIONS CURABLE BY HUMIDITY

摘要

Polysiloxane compositions which harden in the presence of moisture by elimination of alcohols, which have high stability in storage while unvulcanized in the absence of moisture, which exhibit good adhesion to substrates, and which are improved by the presence of stabilizing silyl derivations of N-methyl benzamide contain: (A) 100 parts by weight of a polydimethyl siloxane which contains terminal diorganyloxyorganosilyl or triorganyloxylsilyl groups and which has a viscosity of 0.1 to 100 Pas, (B) 0 to 100 parts by weight of an alpha , omega -bis(trimethylsiloxy)-polydimethyl siloxane which has a viscosity of from 0.04 to 10 Pas, (C) 0 to 5 parts by weight of an alkoxysilane having the formula R1aSi(OR2)4-a, in which R1 is C1-C6 alkyl, C2-C6 alkenyl or C5-C6 aryl; R2 is C1-C6 alkyl, and a is 0 or 1, (D) 0.1 to 5 parts by weight of an aminoalkyl alkoxysilane containing one or more basic nitrogen atoms attached to a silicon atom through at least 3 carbon atoms, (E) 5 to 250 parts by weight of a reinforcing or non-reinforcing filler or filler mixture, (F) 0.01 to 2 parts by weight of an organometallic catalyst and (G) 0.5 to 5 parts by weight of an amidosilane of the formula in which each R3 is the same or different from any other R3 and is C1-C6 alkyl, C2-C6 alkenyl, C5-C6 aryl or unbranched or branched C1-C6 alkoxy; X is a C1-C4 alkyl; and b is 1 or 2.