DIAMOND-COATED MEMBER AND PROCESS FOR THE PREPARATION THEREOF

摘要

The present invention relates to a diamond-coated member characterized by superposing an acicular diamond layer, an intermediate layer formed by a metal belonging to either of the group IIIb, IVa, Va or VIa of the periodic table or by a compound containing the said metal, Si or B, and a non-acicular diamond layer on the surface of a base material and to a process for the preparation of a diamond-coated member characterized in that a diamond layer is formed on the surface of a base material by vapor phase synthesis method; the resulting diamond layer is converted into acicular diamond by exposing the resulting diamond layer to a gas obtainable by exciting an oxygen-containing etching gas; an intermediate layer comprising a metal belonging to either of the group IIIb, IVa, Va or VIa of the periodic table or by a compound containing the said metal, Si or B is formed on the resulting acicular diamond; and the resulting intermediate layer is exposed to a gas obtainable by exciting a raw material gas containing a carbon source gas. The diamond-coated member according to the present invention is useful as cutting tools and abrasion resistant members.