| 摘要 |
<p>PURPOSE:To easily and safely form an electrically conductive homogeneous film with accuracy at a low cost by doping a phthalocyanine pigment electrodeposited on an electrode by a micelle electrolysis method with halogen or a compd. thereof. CONSTITUTION:A surfactant is dissolved in an aq. soln., micelle is formed and a phthalocyanine pigment is dispersed and suspended in the soln. and solubilized with the micelle. A proper electrolyte is added to the resulting micelle soln. and electrolysis is carried out to electrodeposit the pigment on an electrode in the form of a film. In the above-mentioned micelle electrolysis method, the pigment on the electrode is doped with halogen or a compd. thereof by putting the electrode with the electrodeposited pigment in a halogen-contg. soln. and carrying out electrolysis. Halogen may be dissolved in the micelle soln. and electrodeposited on the electrode together with the pigment. A film of the phthalocyanine pigment contg. uniformly dispersed halogen is selectively and surely formed by treatment in the aq. solns.</p> |
