SILBER ENTHALTENDE KATALYSATOREN ZUR HERSTELLUNG VON AETHYLENOXYD.

摘要

A process for manufacturing silver catalysts deposited on a porous refractory support, comprising impregnating a refractory support with a portion of the silver required for the catalyst by immersing the support in a practically anhydrous solution of an organic carboxylic acid salt of silver in an organic liquid which complexes the silver ions, removing excess organic liquid from the support without causing the deposition of metallic silver thereon; depositing the remainder of the silver and at least one promoter selected from cesium, rubidium, or potassium on the support modified by the first silver deposit by immersing said modified support in a practically anhydrous solution of an organic carboxylic acid salt of silver in an organic liquid which complexes the silver ions, said organic liquid containing in the solubilized state, a salt of at least one of the promoters, before transformation of the silver deposited into metallic silver.