发明名称 PRODUCTION OF P-OR M-HYDROXYPHENYLALKYL ALCOHOL
摘要 PURPOSE:To industrially and advantageously obtain a carbonyl compound by treating a p- or m-tert. butoxyphenylalkyl alcohol used as a raw material with a de-tert. butylating agent or adding a de-tert. butylating catalyst thereto and distilling isobutylene out of the system under a reduced pressure. CONSTITUTION:A p- or m-tert.-butoxyphenylalkyl alcohol expressed by formula I (n is 2-5) is treated with a debutylating agent such as hydrochloric acid or sulfuric acid or isobutylene is distilled out of the system in the presence of a de-tert.-butylation catalyst under reduced pressure to provide p-or m- hydroxyphenylalkyl alcohol expressed by formula II. According to the above- mentioned method, operation is readily carried out and the aimed compound is obtained in a high purity. Further, tert. butyl group which is a protecting group of phenolic hydroxyl group can be readily recovered and re-utilized. The aimed compound is useful as an intermediate for agricultural chemical and raw material for liquid crystal polymer.
申请公布号 JPH02218632(A) 申请公布日期 1990.08.31
申请号 JP19890038244 申请日期 1989.02.20
申请人 HOKKO CHEM IND CO LTD 发明人 ARAKI YOSHIHIRO;KUMAMOTO NOBUMITSU;BANNOU TADASHI;WAKABAYASHI SUMIO;UMENO MASAYUKI
分类号 C07C37/16;B01J27/02;B01J27/10;B01J31/02;B01J31/10;C07B61/00;C07C37/055;C07C39/11 主分类号 C07C37/16
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