发明名称 |
PRODUCTION OF P-OR M-HYDROXYPHENYLALKYL ALCOHOL |
摘要 |
PURPOSE:To industrially and advantageously obtain a carbonyl compound by treating a p- or m-tert. butoxyphenylalkyl alcohol used as a raw material with a de-tert. butylating agent or adding a de-tert. butylating catalyst thereto and distilling isobutylene out of the system under a reduced pressure. CONSTITUTION:A p- or m-tert.-butoxyphenylalkyl alcohol expressed by formula I (n is 2-5) is treated with a debutylating agent such as hydrochloric acid or sulfuric acid or isobutylene is distilled out of the system in the presence of a de-tert.-butylation catalyst under reduced pressure to provide p-or m- hydroxyphenylalkyl alcohol expressed by formula II. According to the above- mentioned method, operation is readily carried out and the aimed compound is obtained in a high purity. Further, tert. butyl group which is a protecting group of phenolic hydroxyl group can be readily recovered and re-utilized. The aimed compound is useful as an intermediate for agricultural chemical and raw material for liquid crystal polymer. |
申请公布号 |
JPH02218632(A) |
申请公布日期 |
1990.08.31 |
申请号 |
JP19890038244 |
申请日期 |
1989.02.20 |
申请人 |
HOKKO CHEM IND CO LTD |
发明人 |
ARAKI YOSHIHIRO;KUMAMOTO NOBUMITSU;BANNOU TADASHI;WAKABAYASHI SUMIO;UMENO MASAYUKI |
分类号 |
C07C37/16;B01J27/02;B01J27/10;B01J31/02;B01J31/10;C07B61/00;C07C37/055;C07C39/11 |
主分类号 |
C07C37/16 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|