发明名称 |
Process for preparing carboxylic acids. |
摘要 |
<p>An improved liquid-phase process for preparing carboxylic acids having (n + 1) carbon atoms by rhodium catalysed carbonylation of an alcohol having n carbon atoms is provided. The process is particularily suitable for preparing acetic acid from methanol in commercial carbonylation reactors operating at steady-state with a low standing quantity of water (eg 0.5 to 5% by weight). The improvement lies in carrying out the carbonylation in the presence of an iodide stabiliser (eg lithium iodide) and a Group VI B metal costabiliser. The process can optionally be carried out in the presence of hydrogen.</p> |
申请公布号 |
EP0384652(A1) |
申请公布日期 |
1990.08.29 |
申请号 |
EP19900301655 |
申请日期 |
1990.02.15 |
申请人 |
THE BRITISH PETROLEUM COMPANY P.L.C. |
发明人 |
JONES, MICHAEL DAVID |
分类号 |
C07B61/00;B01J27/12;C07C51/12;C07C53/00;C07C53/08 |
主分类号 |
C07B61/00 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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