发明名称 PROCESS FOR PRODUCING 2-ALKYL- AND 2-(SUBSTITUTED ALKYL) -4-ALKYLTHIO AND ALKYLSULFONYL-BENZOIC ACIDS AND THEIR DERIVATIVES
摘要 A process for production of an alkylthiobenzoate comprising reacting a cyclohexenone having the formula <IMAGE> in which R1 is C1-C6 alkyl; X is alkyl or unsubstituted alkyl; and Y is hydrogen, halogen or alkyl, with a mercaptan having the formula R2SH in which R2 is C1-C4 alkyl, preferably in the presence of an acid catalyst, to form a cyclohexadiene thioether, and dehydrogenating the thioether to produce a thioalkylbenzoate. The thioalkylbenzoate may be further converted by oxidation and/or hydrolysis to a corresponding thioalkyl, alkylsulfinyl or alkylsulfonyl benzoic acid.
申请公布号 AU4942990(A) 申请公布日期 1990.07.10
申请号 AU19900049429 申请日期 1989.11.27
申请人 ICI AMERICAS INC. 发明人 RICHARD W. BROWN
分类号 C07C317/44;C07C323/61;C07C323/62 主分类号 C07C317/44
代理机构 代理人
主权项
地址