发明名称 ENANTIOMERIC SILANES, MODIFIED PACKING MATERIAL, AND USE THEREOF
摘要 Compounds of formula I (I), wherein R1 is C1-C4alkyl,phenyl or benzyl, R2 is C1-C4alkyl,phenyl or benzyl, a is 0, 1 or 2, R3 is linear or branched unsubstituted or OH-substituted C1-C12alkylene or is phenylene, X is -O-, -S- or -NR6, wherein R6 is H, C1-C4alkyl or -CO-R5-OH, b is 0,or b is an integer from 1 to 6 and R4 is linear or branched unsubstituted or OH-substituted C1-C12alkylene, Y is -O-, -S- or -NR7, wherein R7 is H or C1-C4alkyl, R5 is the divalent radical, diminished by the -CO-O group, of a lactone having a total of 4 to 7 ring members and containing at least one chiral carbon atom and corresponding predominantly to an optically active enantiomeric form, and e is an integer from 1 to 10. These compounds are suitable for the preparation of stationary phases for the chromatographic separation of chiral compounds.
申请公布号 CA2005856(A1) 申请公布日期 1990.06.20
申请号 CA19892005856 申请日期 1989.12.18
申请人 CIBA-GEIGY AG 发明人 LOHMANN, DIETER;DAPPEN, RICHARD
分类号 B01J20/291;B01J20/28;B01J20/281;B01J20/32;C07F7/18;G01N30/88;(IPC1-7):C07C37/72;B01D15/08;C07F7/10;C07C209/88 主分类号 B01J20/291
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