| 摘要 |
Water-soluble copper complex formazan compounds which conform to the general formula (1) below and have useful fiber-reactive dye properties and dye carboxamido- and/or hydroxy-containing material, in particular cellulose fibers, in fast blue shades. <IMAGE> (1) <IMAGE> in which: M is hydrogen or a salt-forming metal atom, k, m and n each denote the number zero, 1 or 2, the sum (k+m+n) being equal to 1 to 4, A is a benzene or napththalene ring which additionally can contain the fiber-reactive group -NH-Q and further substituents, B is a benzene or naphthalene ring which additionally contains the fiber-reactive group -NH-Q and further substituents, D is substituted or unsubstituted alkylene of 1 to 8 carbon atoms or is a benzene or naphthalene ring having optionally additional substituents or is a heterocyclic radical, X is a sulfo group or an oxy or carbonyloxy group, r is the number 1 or 2, Q is a radical of the formula (2) <IMAGE> (2) in which Y is halogen, Z is vinyl or a beta -substituted ethyl, G is the thio or an amino group -N(R)- where R is equal to hydrogen or to low, substituted or unsubstituted alkyl or a group -K-Wp defined hereinafter, K is alkylene or arylene or arylene-alkylene or alkylene-arylene whose arylene and alkylene radicals can be substituted and/or interrupted by a hetero group, W is a water-solubilizing group and p is the number 1, 2 or 3, the group -NH-Q is bonded to an aromatic carbon atom of A or B or D or to an aliphatic carbon atom of D or of a substituent on A or B, in the case of r=2, however, not simultaneously to A, B or D.
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