发明名称 |
Synthesis of ethylidene bis-formamide using formic acid |
摘要 |
Ethylidene bis-formamide, a precursor for the monomer N-vinylformamide, is made in high yield by heating together formamide and acetaldehyde in a mol ratio of at least 3:1 and in a reaction mixture which is at least 20 weight percent formic acid. In a preferred procedure the acetaldehyde is added after the formamide has been preheated and formic acid is present. Yields of ethylidene bis-formamide of over 50%, based on the acetaldehyde, are obtained in relatively short reaction times, before loss of substantial amounts of recoverable formamide through hydrolysis.
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申请公布号 |
US4906777(A) |
申请公布日期 |
1990.03.06 |
申请号 |
US19880260090 |
申请日期 |
1988.10.19 |
申请人 |
AIR PRODUCTS AND CHEMICALS, INC. |
发明人 |
PINSCHMIDT, JR., ROBERT K.;NORDQUIST, ANDREW F. |
分类号 |
C07C231/08 |
主分类号 |
C07C231/08 |
代理机构 |
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