发明名称 |
PROCESS FOR PRODUCING A PLASTIC-BOUND GAS DIFFUSION ELECTRODE CONTAINING A MANGANESE OXIDE CATALYST WITH A PREDOMINANT COMPOSITION OF DIMANGANESE TRIOXIDE AND PENTAMANGANESE OCTOXIDE |
摘要 |
In an electrically heated vibratory screw conveyor, manganese carbonate (MnCO3. x H2O) is thermally decomposed at about 500 DEG C to give the abovementioned manganese oxide catalyst which is then processed by dry, intensive mixing with a carbon-containing conductivity agent (carbon black, graphite, activated carbon) and PTFE as binder to give a highly active electrode mass which can be rolled into a carrier net of Ni or Ag. A two-stage mixing process is particularly advantageous in which the catalyst powder is initially premixed with only a little conductivity agent and binder, compacted and granulated. In a second mixing step, the granules are combined with the larger remainder of the intended quantity of conductivity agent and binder. The finished gas diffusion electrode has a biporous structure of hydrophilic and hydrophobic pore channels, which structure is highly advantageous for transport processes and the electrochemical conversion. The electrode can be used in fuel cells, chloro-alkali electrolysis cells and atmospheric oxygen cells. |
申请公布号 |
EP0297377(A3) |
申请公布日期 |
1989.12.06 |
申请号 |
EP19880109767 |
申请日期 |
1988.06.20 |
申请人 |
VARTA BATTERIE AKTIENGESELLSCHAFT |
发明人 |
SAUER, HANS;WINSEL, AUGUST, PROF. DR. DIPL.-PHYS. |
分类号 |
C25B11/06;B01J23/34;B01J37/08;C25B11/00;C25B11/04;C25B11/16;H01M4/88;H01M4/90 |
主分类号 |
C25B11/06 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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