发明名称 METHOD AND APPARATUS FOR MEASURING SUPPRESSOR TYPE ION-PAIR CHROMATOGRAPH
摘要 PURPOSE:To make it possible to perform measurement in a low pH region and to expand specimens to be applied, by using carbonate solution or hydrogen carbonate solution of ion reagent as an eluant. CONSTITUTION:An eluant 1 incorporating carbonate or hydrogen carbonate of ion reagent is sent into a separating column 4, a cation exchange film suppressor 5 and a conductivity detector 8 through an injection valve 3 art a constant speed with a constant quantity pump 2. H2SO4 solution 7 is always sent to the outside of the cation exchange film in the suppressor 5 with a constant quantity pump 6. Therefore, the solution is always regenerated as an H<+> type in the suppressor 5. The eluate which is sent into the suppressor is transformed into H2CO3 through cation exchange. Therefore, background conductivity which is measured by using a conduction detector 8 is decreased. Thus, the increase in conductivity owing to the elution of a specimen component which is injected through the valve 3 is detected with the detector 8 highly accurately at high sensitivity.
申请公布号 JPH01299457(A) 申请公布日期 1989.12.04
申请号 JP19880128365 申请日期 1988.05.27
申请人 HITACHI LTD 发明人 TAKEHARA HIROKO
分类号 G01N30/02;B01D15/08;G01N30/26 主分类号 G01N30/02
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