PROCESS FOR PRODUCING HIGH IMPACT STYRENE RESIN BY CONTINUOUS BULK POLYMERIZATION

摘要

A process for producing a high impact styrene resin which comprises continuously polymerizing a styrene monomer in bulk in the presence of a rubbery polymer, wherein a polymerization line is used which is comprised of an initial polymerization line (II) consisting of at least one tubular reactor having an inlet following the outlet of a starting material feed line (I) and static mixing means therein, a main polymerization line (III) consisting of at least one tubular reactor having an inlet following the outlet of the initial polymerization line (II) and static mixing means, and a recycle line (IV) which branches on the way in a passage ranging from the outlet of the initial polymerization line to the inlet of the main polymerization line (III) and returns to the front of at least one tubular reactor in the initial polymerization line (II) ; and part or a greater part of a flow of the initial-stage polymer solution leaving the outlet of the initial polymerization line (II) is recycled via the recycle line (IV) to allow it to join a flow of a starting material solution fed from the starting material feed line (I) or the flow of the initial polymerization solution being in the process of initial polymerization and the initial polymerization is further allowed to proceed in the initial polymerization line (II), and in the meantime, the initial polymerization solution not recycled through the recycle line is polymerized in the main polymerization line (III).