发明名称 PREPARATION OF ETHYLDIPHENYLETHANES
摘要 PURPOSE:To readily provide the subject compound, by subjecting diphenylethane and polyethylbenzenes by-produced in a process for producing ethylbenzene from benzene and ethylene to a transalkylation reaction in the presence of a Friedel-Crafts catalyst. CONSTITUTION:1mol of diphenylethane and 1-5mols (expressed in terms of ethyl groups) of polyethylbenzene by-produced in a process for producing ethylbenzene by alkylating benzene with ethylene are subjected to a transalkylation reaction in the presence of a Friedel-Crafts catalyst such as AlCl3 at 0-150 deg.C preferably for 0.5-6hr. After the reaction finishes, the Friedel-Crafts catalyst is removed from the reaction product and a distrillation fraction containing 1-phenyl-1-ethylphenylethane, etc., is subsequently separated by distillation to provide the objective compound which is useful as a thermal medium, solvent for pressure-sensitive copying paper, insulating oil, lubricating oil for hydraulic fluids, etc. The by-produced ethylbenzene is useful as a raw material for the production of styrene.
申请公布号 JPH01261336(A) 申请公布日期 1989.10.18
申请号 JP19880091148 申请日期 1988.04.13
申请人 MITSUBISHI PETROCHEM CO LTD 发明人 TAKAHASHI HIDEYUKI;HARADA HIROYUKI
分类号 C07C6/12;B01J27/125;C07B61/00;C07C1/00;C07C15/16;C07C15/18;C07C67/00 主分类号 C07C6/12
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