发明名称 Selective process for preparing 2,4- or 3,6-di-substituted phenol compounds.
摘要 <p>The invention provides a selective process for preparing a 2,4- or 3,6-di-substituted phenol compound which comprises reacting an olefin compound of the formula: <CHEM> wherein R<1> is hydrogen, halogen, alkyl, halogen substituted-alkyl, aryl, halogen substituted-aryl or alkyl substituted-aryl; and R<2>, R<3> and R<4> are the same or different and each is hydrogen, halogen, alkyl, halogen substituted-alkyl or aralkyl; with a phenol compound of the formula: <CHEM> wherein R<5> is hydrogen, hydroxy, halogen, alkyl, halogen substituted-alkyl, alkoxy or -C(R<6>)(R<7>)CH(R<8>)(R<9>) (wherein R<6> is hydrogen, halogen, alkyl, halogen substituted-alkyl, aryl, halogen substituted-aryl or alkyl substituted-aryl; and R<7>, R<8> and R<9> are the same or different and each is hydrogen, halogen, alkyl, halogen substituted-alkyl or aralkyl), in the presence of a phosphorus compound and a carboxylic acid compound as catalysts.</p>
申请公布号 EP0335674(A2) 申请公布日期 1989.10.04
申请号 EP19890303081 申请日期 1989.03.29
申请人 YOSHITOMI PHARMACEUTICAL INDUSTRIES, LTD. 发明人 KINISHI, RYOICHI;WAKAMATSU, SHUICHI;IKE, TETSUJI
分类号 B01J31/04;C07B61/00;C07C37/14;C07C39/06;C07C39/15 主分类号 B01J31/04
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