发明名称 Separation of actinides from lanthanides
摘要 An organic extracting solution and an extraction method useful for separating elements of the actinide series of the periodic table from elements of the lanthanide series, where both are in trivalent form. The extracting solution consists of a primary ligand and a secondary ligand, preferably in an organic solvent. The primary ligand is a substituted monothio-1,3-dicarbonyl, which includes a substituted 4-acyl-2-pyrazolin-5-thione, such as 4-benzoyl-2,4-dihydro-5-methyl-2-phenyl-3H-pyrazol-3-thione (BMPPT). The secondary ligand is a substituted phosphine oxide, such as trioctylphosphine oxide (TOPO).
申请公布号 US4867951(A) 申请公布日期 1989.09.19
申请号 US19880176131 申请日期 1988.03.31
申请人 THE UNITED STATES OF AMERICA AS REPRESENTED BY THE UNITED STATES DEPARTMENT OF ENERGY 发明人 SMITH, BARBARA F.;JARVINEN, GORDON D.;RYAN, ROBERT R.
分类号 C01F17/00;C22B3/40 主分类号 C01F17/00
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