发明名称 SELECTIVE PRODUCTION OF P-ISOBUTYLBENZENE
摘要 PURPOSE:To use a specific crystalline aluminosilicate zeolite or a previously modified substance thereof as a catalyst in bringing isobutylbenzene into contact with an ethylating agent and selectively obtaining the present substance. CONSTITUTION:Isobutylbezene is brought into contact with an ethylating agent (e.g., ethylene or ethanol) to provide the present substance. In the process, a crystalline aluminosilicate zeolite having characteristics of 2-5000 (alpha) value, >=1g xylene adsorptivity based on 100g zeolite, >=12 silica/alumina ratio, 1-12 control index, etc., is used as a catalyst to carry out reaction at 300-500 deg.C and 2.5-7.5 weight hourly space velocity and 2-8 molar ratio of isobutylbenzene/ethylating agent under 0.1-100atm. The catalyst may be previously modified by a method for combining the crystalline aluminosilicate with an oxide of P, Mg, B, etc., steaming or previously coking the aluminosilicate, etc.
申请公布号 JPH01228921(A) 申请公布日期 1989.09.12
申请号 JP19880055516 申请日期 1988.03.09
申请人 NIPPON PETROCHEMICALS CO LTD 发明人 SHIMIZU ISOO;TOKUMOTO YUICHI
分类号 C07C1/20;B01J29/40;B01J29/70;C07B61/00;C07C1/00;C07C1/30;C07C1/32;C07C2/66;C07C15/02;C07C67/00 主分类号 C07C1/20
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