| 摘要 |
1353636 Microcapsules FUJI PHOTO FILM CO Ltd 30 June 1971 [2 July 1970] 30706/71 Heading B8C In processes of preparing microcapsules by coacervation of one or more chemically hardenable hydrophilic colloids such as gelatine followed by gelling and subsequent hardening, there is added to the coacervated product a "shockproofing agent" and a compound having a repeating structural unit containing at least one group of the formula -COOX where X is H, NH 4 or an alkali metal, at a temperature below the gelling point of the hydrophilic colloid before the hardening step. Preferred compounds are those of formulae wherein, in Formula I, R 1 is H or Me, R 2 is halogen, COR or COOR (R being H, alkyl or aryl), X is H or an alkali metal or NH 4 and n is an integer and in Formula II, R 1 is H, halogen, CN, alkyl, aryl, COR or COOR (R being as above), X is H, alkali metal or NH 4 and n is an integer. Examples of such compounds are maleic anhydride copolymers, e.g. with styrene, polyethylene, methyl vinyl ether or vinyl acetate and similar copolymers of acrylic and methacrylic acids as well as methacrylic polymer. Suitable "shock-proofing agents" are cellulose and starch derivatives having anionic functional groups, pectin, pectinic acid, vinylbenzene sulphonate copolymer, acrylic copolymers, naphthalene sulphuric acid/ formalin condensates, nucleic acids, polyamino acids and polyethylene oxide. The core material to be encapsulated may be any solid or liquid hydrophobic material, e.g. an oil. |
