发明名称 Preparation of homopolymers and copolymers of ethylene by means of a Ziegler catalyst system
摘要 Ethylene is polymerized using a Ziegler catalyst system consisting of (1) a titanium catalyst component and (2) an aluminum catalyst component, the component (1) used being the product (VI) which is obtained by a method in which (1.1) first (1.1.1) a carrier (I) and (1.1.2) a solution (II) of (IIa) a solvent, (IIb) a titanium trichloride and (IIc) magnesium chloride are combined with formation of a dispersion (III) and the latter is evaporated down with formation of an intermediate (IV), and (1.2) then (1.2.2) the intermediate (IV) obtained from (1.1), and (1.2.2) an aluminum component (V) consisting of (1.2.2.1) a complex of a certain oxacycloalkane and a certain aluminum compound and (1.2.2.2) if necessary, a certain free aluminum compound are combined, the resulting product (VI) being the catalyst component (1). In this process, a component (1) is employed which has been prepared using, in (1.1) under (1.1.2), a solution (II) which (i) contains a ketone as (IIa) and (ii) additionally contains (IId) a certain low molecular weight polymeric compound.
申请公布号 US4845177(A) 申请公布日期 1989.07.04
申请号 US19870107996 申请日期 1987.10.14
申请人 BASF AKTIENGESELLSCHAFT 发明人 VOGT, HEINZ;SCHAUSS, ECKARD;SCHWEIER, GUENTHER
分类号 C08F4/50;C08F4/64;C08F10/00 主分类号 C08F4/50
代理机构 代理人
主权项
地址