发明名称 Catalytic process for producing cross-linked resin from phenolic compound and bis-oxazoline
摘要 A process for producing a cross-linked resin which comprises: reacting at least one phenolic reactant selected from the group consisting of (a) a compound having phenolic hydroxyls and having the general formula: HO-Ar-OH wherein Ar represents a divalent aromatic group composed of single or condensed aromatic rings, or a divalent aromatic group composed of two or more aromatic rings connected by C-C covalent bond, or a divalent aromatic group composed of two or more aromatic rings connected by a divalent hydrocarbon group or a divalent group selected from the group consisting of carbonyl, thioether, ether and amide group, and wherein the aromatic ring may bear additional hydroxyls or substituents which are inactive to the bis(2-oxazoline) compound, and (b) a polymer having not less than two phenolic hydroxyls in the molecule. with a bis(2-oxazoline) compound in a molar ratio of the bis(2-oxazoline) compound to the phenolic reactant not less than about 1, in the presence of a catalyst selected from the group consisting of phosphorous acid, organic phosphites and oxazoline ring-opening polymerization catalysts at elevated temperatures.
申请公布号 US4843142(A) 申请公布日期 1989.06.27
申请号 US19860947412 申请日期 1986.12.24
申请人 TAKEDA CHEMICAL INDUSTRIES, LTD. 发明人 SANO, YASUO;SHIRAHAMA, KOUICHI;HIRONO, TAKAHIKO
分类号 C08G69/44 主分类号 C08G69/44
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