PRODUCTION OF SYNTHETIC GAS

摘要

Synthesis gas, fuel gas, or reducing gas is produced by the noncatalytic partial oxidation of a sulfur-containing liquid hydrocarbonaceous fuel or a slurry of sulfur-containing solid carbonaceous fuel with a free-oxygen containing gas in the free-flow reaction zone, or first reaction zone R1, of a refractory lined gas generator at an autogenous temperature in the range of about 1900 DEG F to 2900 DEG F and above the ash fusion temperature of the slag formed in the reaction zone, so that a high proportion of the carbon in the fuel feed to the reaction zone is converted into carbon oxides. At least a portion of the hot effluent gas stream from the reaction zone is passed through a free-flow radiant cooler, or second reaction zone R2, in admixture with an iron-containing additive or in admixture with a second portion of the fuel and an iron-containing or calcium-containing additive. In the radiant cooler or second reaction zone R2, at least a portion of the sulfur-containing gases, e.g. H2S and COS react with the iron-containing or calcium-containing additive to produce particulate matter comprising iron oxysulfide or calcium sulfide. Further, a portion of this newly formed particulate matter and/or the iron-containing or calcium-containing additive combine with molten slag and/or ash in the hot raw gas stream passing through the radiant gas cooler or the second reaction zone R2. The slag produced thereby has a reduced ash fusion temperature and a reduced viscosity, or the fly-ash which is produced thereby has an increased ash softening temperature. The product gas stream discharged contains a reduced amount of sulfur-containing gases.