发明名称 METHOD FOR DECOMPOSING TERT-BUTYLPHENOLS
摘要 PURPOSE:To obtain phenols and isobutylene in high yield and purity, by efficiently decomposing the title compound using a catalyst prepared by heat-treating aluminum phenoxides or alkoxides with a protonic compound. CONSTITUTION:tert-Butyl phenols are efficiently decomposed in the presence of a catalyst prepared by heat-treating aluminum phenoxides or alkoxides with a protonic compound, preferably alcohols or water, preferably at 40-80 deg.C temperature without deactivating the catalyst to recover phenols and isobutylene in high yield and purity, especially useful raw materials are economically recovered from by-products of low utilization value secondarily formed in synthesizing specific tert-butylphenols from the phenols and isobutylene. Furthermore, no substituent group other than tert-butyl groups bound to the tert-butylphenols is decomposed.
申请公布号 JPH01128939(A) 申请公布日期 1989.05.22
申请号 JP19870285002 申请日期 1987.11.11
申请人 MITSUI PETROCHEM IND LTD 发明人 MATSUNAGA FUJINAO;FUKUHARA HIROSHI;SATO NORIKO
分类号 C07C1/20;B01J31/02;C07B61/00;C07C1/00;C07C11/09;C07C27/00;C07C37/50;C07C39/04;C07C67/00 主分类号 C07C1/20
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