发明名称 Process for the preparation of arylimides of perylene-3,4,9,10-tetracarboxylic acid
摘要 Process for the preparation of compounds of the formula (1) <IMAGE> (1) in which R1 denotes a phenyl or naphthyl radical which can be substituted by alkyl, cycloalkyl, alkoxy, aryloxy, arylazo or nitro groups or halogen atoms, and R2 denotes a hydrogen atom or a phenyl or naphthyl radical which can be substituted by alkyl, cycloalkyl, alkoxy, aryloxy, arylazo or nitro groups or halogen atoms, or denotes an alkyl (C1-C8) radical, by condensation, at between 100 DEG C. and 300 DEG C., of perylene-3,4,9,10-tetracarboxylic dianhydride or a monoanhydride monoimide of the formula (2) <IMAGE> (2) in which R2 has the abovementioned meaning, with an arylamine of the formula (3) R1-NH2 (3) in which R1 has the abovementioned meaning, in the presence of dialkylamines of the formula (4) <IMAGE> (4) in which R' and R'' denote straight-chain alkyl C1- C6 or branched alkyl C3-C6 or cycloalkyl C5-C6 groups, which can be substituted by hydroxyl, alkoxy C1-C4, alkyl C1-C4 amino, or phenyl or naphthyl groups which can be substituted on the aromatic nucleus by alkyl C1-C4, alkoxy C1-C4 or alkyl C1-C4-amino groups or halogen atoms, and in which R' and R'' can form with the nitrogen atom a 5- or 6-membered heterocyclic ring.
申请公布号 US4831140(A) 申请公布日期 1989.05.16
申请号 US19860850847 申请日期 1986.04.11
申请人 HOECHST AKTIENGESELLSCHAFT 发明人 SPIETSCHKA, ERNST;TROESTER, HELMUT
分类号 C09B5/62 主分类号 C09B5/62
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