发明名称 Process for the separation of dihydroxybenzene isomers
摘要 This invention comprises a process for separating isomers of dihydroxybenzene (DHB) from a feed mixture comprising at least two of said isomers, which process comprises contacting the mixture at adsorption conditions with an adsorbent comprising a Y type zeolite cation exchanged with a cation in the group Ca, Ba or Li, thereby selectively adsorbing o-DHB (catechol), or K, thereby selectively adsorbing p-DHB (hydroquinone). In the case where all three isomers are present in the feed, a cation from the first group is used, the remainder of the feed mixture is removed from the adsorbent and o-DHB is recovered by desorption at desorption conditions with methanol. P-DHB is recovered from the remainder by adsorption with the same or other adsorbent listed above and desorption at desorption conditions with ethanol.
申请公布号 US4827049(A) 申请公布日期 1989.05.02
申请号 US19880173853 申请日期 1988.03.28
申请人 UOP 发明人 ZINNEN, HERMANN A.
分类号 C07C37/82;(IPC1-7):C07C37/68 主分类号 C07C37/82
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