发明名称 Friedel-crafts preparation of aromatic ketones
摘要 Aromatic carbonyl compounds, in particular arylene ether ketones, are prepared by reacting an appropriate reagent system in the presence of free Lewis acid and a complex between a Lewis acid, for example, aluminum trichloride, and a Lewis base, for example, N,N-dimethylformamide, and, optionally, a diluent, such as methylene chloride. The process is particularly advantageous for the preparation of substantially or all para-linked arylene ether ketones as the presence of the Lewis acid/Lewis base complex markedly reduces alkylation and ensures the substantial absence of ortho substitution.
申请公布号 US4814508(A) 申请公布日期 1989.03.21
申请号 US19880175646 申请日期 1988.03.21
申请人 RAYCHEM CORPORATION 发明人 GORS, HEINRICH C.;HORNER, PATRICK J.;JANSONS, VIKTORS
分类号 C07C49/784;C07C45/00;C07C45/45;C07C45/46;C07C45/47;C07C49/76;C07C49/80;C07C49/813;C07C49/84;C07C51/00;C07C51/58;C07C63/00;C07C67/00;C07C313/00;C07C319/20;C07C323/22;C07C323/65;C07D521/00;(IPC1-7):C07C107/06;C07C49/83 主分类号 C07C49/784
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