发明名称 PROCESS FOR PRODUCING STEREOREGULAR POLYMERS HAVING A NARROW MOLECULAR WEIGHT DISTRIBUTION
摘要 Stereoregular polymers having a molecular weight distribution of less than 5.0 and an isotactic index in excess of 96 percent are produced by polymerizing an alpha-olefin having 3 to 8 carbon atoms in a low pressure gas phase fluid bed process at a temperature in excess of 80 DEG C employing a heat stable catalyst system comprising (a) a solid catalyst component containing magnesium, titanium, halide and a polycarboxylic acid ester containing two coplanar ester groups attached to adjacent carbon atoms, as inside electron donor, (b) an organoaluminum cocatalyst, and (c) a silicon compound containing a silicon-oxygen-carbon linkage, as outside electron donor.
申请公布号 ZA8803535(B) 申请公布日期 1989.01.25
申请号 ZA19880003535 申请日期 1988.05.18
申请人 UNION CARBIDE CORPORATION 发明人 ROBERT CONVERSE BRADY III;FRANCIS GREGORY STAKEM;HAN TAI LIU;ALLEN NOSHAY
分类号 C08F4/649;C08F2/34;C08F4/60;C08F4/64;C08F4/654;C08F10/00;C08F10/06 主分类号 C08F4/649
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