摘要 |
<p>SILANES AND COMPOSITIONS PREPARED THEREFROM This invention relates to silanes of the general formula RnSi(OCR?COZR)4-n where R represents the same or different monovalent hydrocarbon radicals or substituted monovalent hydrocarbon radicals, R1 is hydrogen or the same as R, Z is oxygen or the group , where R1 is the same as above, n is 0 or 1 and oligomers thereof. These silanes are prepared by reacting silanes of the general formula RnSiX4-n where R and n are the same as above and X represents the same or different hydrolyzable atoms or condensable groups other than RCOCR?CO groups, with alpha-hydroxycarboxylic acid esters or amides. The silanes, which have at least three condensable groups per molecule, may be mixed with a diorganopolysiloxane containing terminal condensable groups and at least one additional substance to prepare compositions which are storagestable under anhydrous conditions, but crosslink when exposed to moisture at room temperature to form elastomers.</p> |