发明名称 PRODUCTION OF AROMATIC HYDROCARBON HAVING ACYLOXY SUBSTITUENT
摘要 PURPOSE:To obtain the titled compound useful as a raw material for synthetic polymer, intermediate for pharmaceuticals, etc., with simple process in one step, by using an aromatic hydrocarbon having isopropyl substituent as a raw material and reacting the hydrocarbon in the presence of mercaptans, carboxylic acid, acylation agent, etc. CONSTITUTION:An aromatic hydrocarbon having isopropyl substituent (e.g. isopropylbenzene or p-cymene) is used as a raw material and is made to react at 20-150 deg.C, preferably 40-100 deg.C in the presence of mercaptans, carboxylic acid, acylation agent and molecular oxygen to obtain the objective compound. The mercaptans are e.g. nitrophenyl mercaptan of an amount of preferably 0.1-1.0mol. per 1mol. of the raw material. The carboxylic acid and the acylation agent are e.g. acetic acid and hydride of the carboxylic acid, respectively, and the amounts are preferably 0-10mol. and 2-10mol. per 1mol. of the raw material, respectively.
申请公布号 JPS63303948(A) 申请公布日期 1988.12.12
申请号 JP19870138907 申请日期 1987.06.04
申请人 MITSUI PETROCHEM IND LTD 发明人 ISHIGURO MASAHARU;MIKI HISAYA
分类号 C07C67/00;C07C69/035 主分类号 C07C67/00
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