发明名称 Hot melt adhesive containing a silane grafted hydrogenated block polymer
摘要 A sealant composition comprising: (a) 100 parts by weight of a silane functionalized polymer component which is prepared by reacting enough silane of the general formula R R'n SiY3-n (where n equals 0, 1 or 2 and where R is a non-hydrolyzable organic group which is capable of grafting onto the polymer, R' is a non-hydrolyzable organic group incapable of grafting onto the polymer and Y is a hydrolyzable organic group) with a polymer component to thereby functionalize the polymer component and provide a resultant sealant composition with adhesion which is resistant to deterioration in the presence of water; said polymer component comprising an A'B' block copolymer, a multiblock copolymer having at least two end blocks A and at least one midblock B, or mixtures of an A'B' block copolymer and the multiblock copolymer wherein: the A' and A blocks comprise monoalkenyl arene blocks and the B' and B blocks comprise substantially completely hydrogenated conjugated diene polymer blocks, and the average molecular weight of the A and A' blocks is greater than the minimum molecular weight needed to obtain microphase separation and domain formation of the A and A' blocks, and is less than the maximum molecular weight which would render the polymer incapable of being melt processed; the multiblock copolymer comprises a monoalkenyl arene content no more than a maximum weight percent needed to retain a modulus suitable as a sealant for the resultant composition and no less than a minimum weight percent needed to obtain the desired phase separation and the desired minimum cohesive strength for the resultant composition; (b) an amount of a midblock compatible component wherein said midblock compatible component is at a concentration to maintain the resultant composition in a plyable condition at room temperture and to maintain the glass transition temperature of the resultant composition below 10 DEG C.
申请公布号 US4783504(A) 申请公布日期 1988.11.08
申请号 US19860835090 申请日期 1986.02.28
申请人 SHELL OIL COMPANY 发明人 ST. CLAIR, DAVID J.;CHIN, STEVEN S.;GELLES, RICHARD
分类号 C08F285/00;C08F287/00;C09J151/00;C09K3/10;(IPC1-7):C08L51/00;C08L53/02 主分类号 C08F285/00
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